4.7 Novel Neutron Technique for Monitoring the State of Drying in Heat-Resistant Vessels for Carrying Molten Steel

Fig. 4-13

A heat-resistant vessel for carrying high temperature molten steel refined in a steel converter to a casting process

The vessel (about 4 m both in height and outer diameter) consists of an iron plate on the outer surface and a thick refractory inside (brightly shining part). A jet from the lid at the upper side is burner gas. The lid is closed during refractory drying.

Fig. 4-14

The model experiment apparatus used for the development of a high sensitivity moisture gauge

The selection of source-detector distance, size and kind of neutron reflector and/or moderator is important, particularly to measure the low moisture content in the refractory through a thick iron plate from the outside.

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Fig. 4-15

The change of neutron counts recorded during refractory drying

The increase of the neutron counts in a range from 9 to 16 h after the start of heating shows that the same water content was measured with a higher efficiency because the water in the refractory was coming close to the outer surface of the vessel due to the burner gas heating from inside. After about 40 h elapsed, the result shows a sufficiently dried state reached.

Huge heat-resistant vessels are employed to transport molten iron or steel in ironworks. Special refractory material, covering the inner surface of a thick iron vessel-wall, should be renewed when damage reaches a serious stage. In the process of renewal, a wet material mixture, densely coated on the surface, is dried with a gas burner for a long time (Fig. 4-13). Up until now, it was difficult to keep the drying process at an optimum condition which is important for making a refractory of high quality, due to the lack of a means to directly measure moisture in the wet refractory.
A mobile moisture gauge with high sensitivity has been developed which can measure even a very low content of moisture in the refractory. In a model experiment (Fig. 4-14), basic characteristics of the moisture gauge were examined in different conditions of source-detector distance, neutron reflector, where a polyethylene plate containing plenty of hydrogen was used instead of water in the vessel. The measurement sensitivity of the developed gauge is about six times higher than that of a conventional one, by the effective use of neutron multi-reflection and moderation.
Application experiments have been carried out at an actual spot of refractory drying, the gauge being placed on the outer surface of a vessel for carrying molten steel. The water in the wet refractory moves toward the outer side as heat drying progresses, and is finally released as steam through small holes in the iron wall. As shown in Fig. 4-15, the change in neutron counts clearly indicates this phenomenon. Remarkably different patterns of changes have been observed at different portions of the vessel wall.
This new technique is expected to be useful also for the diagnosis and improvement of many other drying processes of the refractory, etc.

Reference
H. Tominaga et al., Development of High-Sensitivity Hydrogen or Moisture Gauges with a Low-Activity-Isotope Neutron Source, Proc. 22nd Conf. on Radiation and Radioisotopes, A340 (1996).

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